For these reasons, research on the new materials to build up efficient thermoelectric devices is a scientific subject of current interest [10, 11]. Recently, several oxides such as NaCoO 2 , Ca 3 Co 4 O 9 , Sr 1−x La x TiO 3 , La 1−x Sr x CoO 3 , Nd 1−x Ca x CoO 3 , or Ca 0.8 Dy 0.2 MnO 3  have shown excellent thermoelectric properties. More precisely,
perosvkite-type transition metal oxide single crystals have depicted large thermoelectric responses . The electrical properties of La 1−x A x MnO 3 (A = Ca, Sr, Ba, and Pb) NVP-BGJ398 perosvkite-type oxides are related to their stoichiometry . Significant variations appear when the degree of substitution of the alkali-earth element for La varies from 0% to 50% . The novelty of perovskite-type oxides is due to their low cost, non-toxicity, and possibility of being used for high-temperature applications. The origin of the thermoelectric properties in these oxides is not yet fully understood, but it could be related to the high spin-orbit interaction as well as the large electron effective mass . In 1993, the work of Hicks and Dresselhaus  suggested that the morphology of a thermoelectric system can be used to improve both the electronic transport and the phonon scattering. Nanostructuration can increase ZT over unity by changing σ and S independently. The density of electronic states in a nanostructured system,
when the Fermi energy is Cisplatin order close to a maximum in the density of electronic states, depicts usually sharp peaks and theoretically larger Seebeck coefficients than the same material in bulk . Furthermore, the phonon dynamics and heat transport in a nanostructured system can be suppressed by means of size effects. Nanostructures with one or more dimensions smaller than the phonon mean free path (a phonon glass) but larger than that of electrons (electron crystal) will Acalabrutinib manufacturer noticeably reduce the thermal conductivity κ without affecting much the electrical transport. In other words, phonon transport will be strongly disturbed, while the electronic transport can remain bulk-like
Baricitinib in nanostructured systems. In this report, La 1−x Ca x MnO 3 nanocrystals have been obtained by the hydrothermal method as a function of the Ca content. Several heat treatments have been made to determine the temperature when the perosvkite phase is obtained. Scanning electron microscopy and X-ray diffraction studies have been used to determine the perosvkite phase. The electrical conductivity and Seebeck coefficient have been determined as a function of temperature in order to analyze their thermoelectric performance. Methods Materials The reactants MnCl 2·4H 2O, Ca(NO 3) 2, La(NO 3) 3, KMnO 4 and KOH were purchased from Sigma Aldrich Co., Madrid, Spain. Synthesis of La 1−x Ca x MnO 3nanostructures La 1−x Ca x MnO 3 samples with x=0.005,0.05,0.1 and 0.5 have been prepared by a conventional hydrothermal treatment [20–22].